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materials does not change and remains invariant when the dispersion, specific surface area of the particles and this surface
places of the components change, i.e. state.
ʎ = ʎ , ʎ = ʎ , ʎ , (2) These features are decisive in the polymer structure formation, and
hence its properties, including thermal conductivity [1; 2].
where ʎ - is an effective thermal conductivity PCM;
ʎ , ʎ - is thermal conductivity of the polymer and filler, References:
respectively. [1] Karpinos D. M., Tuchinsky L. I., Sapozhnikov A. V.
and other Compositional materials in technology. -
If the PCM has a filler content of 0,5 < < 1by volume, Kiev: Technique, 1985. - 152 p.
then the polymer is the binder. That is, in such a material,
the volume bulk is occupied by filler, which particles are [2] Godovskiy Yu. K. Thermal physics of polymers, -M.:
interconnected by a thin layer of polymer [2]. A distinctive Chemistry, 1982.- 280 p.
feature of the structure of such a PCM model is that the [3] Feklina L. I. Influence of heat treatment and fillers on
components in it are not geometrically equal, i.е. the structure and thermophysical properties of
ʎ эфф = ʎ , ʎ ≠ ʎ , ʎ (3) polyvinylidene fluoride: Dis. ... Candidate of Physics and
Mathematics-Kiev: 1979. - 190 p.
A number of works, including [3; 4-7], are devoted to the [4]
experimental study of the thermal PCM conductivity based on Kosmynin V. P. Investigation of the structure and some
mechanical properties of polyvinylidene fluoride:
crystallizing polymers and dispersed fillers. Reviews of
experimental and theoretical works available in the Abstract of the thesis... Candidate of Phys. -math.
literature devoted to this problem are carried out in [2-9]. Sciences. - Kiev: 1972. - 22 p.
As is known | 2; 5; 8], the main physicochemical characteristics
of polymer fillers are: the filler type, the filler particles shape,
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